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Abstract


SYNTHESIS AND CHARACTERIZATION OF FE(III) METAL COMPLEXES OF SULFAMOİL BENZOIC ACID DERİVATIVES
Sulfamoylbenzoic acid derivatives and metal complexes are well known for their biological activities, such as antifungal, anti-inflammatory, antimicrobial, antidiabetic, pain reliever, infection therapy, diuretic, meniscus, enzyme inhibitor and rheumatism treatment. The structures simple metal {Cu(II), Zn(II), Ag(I), U(IV), Lu, Y, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Sn} and mixed ligand complexes {Cu(II)} of 4-sulfamoylbenzoic acid, simple metal and mixed ligand Cu(II) complexes of 2-methoxy-5-sulfamoylbenzoic acid and Zn(II) complex of 2,4-dikloro-5-sulfamoylbenzoic acid are explained by various spectroscopic methods in literature. The simple metal complexes of 4-kloro-3- sulfamoylbenzoic acid have not found in literature. In this study, four new Fe(III) complexes (Fe4sba, Fe2MeO5sba, Fe4Cl3sba ve Fe24Cl5sba) of 4-sulfamoylbenzoic acid, 2-methoxy-5-sulfamoylbenzoic acid, 2,4-dikloro-5- sulfamoylbenzoic acid and 4-kloro-3-sulfamoylbenzoic acid have been prepared and characterized by elemental, FTIR, magnetic and molar conductivity measurements.

Keywords
Sulfamoilbenzoic Acid, Complex of Fe(III), Synthesis and Characterization.



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